> Duplex Stainless Steels

Duplex stainless steel

Features

    Duplex stainless steel combines the advantages of ferrite and austenite. Chromium, nitrogen, of high molybdenum content, these steels have good corrosion resistance. Duplex helps organizations achieve high strength and high resistance to stress corrosion cracking performance. Duplex stainless steel also has good weldability.

  • Excellent corrosion resistance, high resistance to stress corrosion cracking and corrosion fatigue properties
  • High mechanical strength, good wear resistance and fatigue resistance
  • Low thermal expansion

 

Chemical compositions and Mechanical properties 
Material Cr Ni  Mo N PRE Y.S. 
MPa
T.S. 
MPa
E.L. 
HB 
UNS S32101 21 1 0.3 0.2 26 530 700 30 230
UNS S32304 23 4 0.3 0.1 26 400 600 25 225
UNS S32205 22 5 3 0.2 35 450 655 25 250
UNS S32750 25 7 4 0.25 42 550 795 15 255

  

Equivalent Grades in different countries: 

Material Grade USA Japan Germany Europe
UNS   AISI/SAE JIS DIN EN
S32900 329 329 SUS329J1 X3CrNiMoN27-5-2 1.4460
S31803 F51/2205 - SUS329J3L X2CrNiMoN22-5-3 1.4462
S32205 F60 - SUS329J3L X2CrNiMoN22-5-3 1.4462
S32550 F61 - SUS329JL2 X2CrNiMoCuN25-6-3 1.4507
S32750 F53/2507 - - 25Cr-7Ni-4Mo-0.28N-Cu 1.4410
S32760 F55 - - X2CrNiMoCuWN25-7-4 1.4501
 

 

 

Metallography

  Duplex Stainless Steel can get almost the same amount of Ferritic and Austenite under annealed condition. Duplex Stainless Steel can generate phase separation phenomenon easier than Austenite, embrittlement and redusce the corrosion resistant. Embrittlement occurred when the temperature is on 600~950℃ and 350~525℃. Therefore, it should be avoided under this temperature for a long time. In the operation of normal and heat treatment, the risk for embrittlement is low. 

Corrosion Resistant

  Pitting Resistance Equivalent PRE =%Cr + 3 , 3x % Mo + 1 6x % N. This value provides a simple way to identify the corrosion resistant. Larger value shows the better corrosion resistant. Duplex Stainless Steel provides a very wide range of corrosion resistant in varios environments. It is generally considered to have a better corrosion resistant if the corrosion is less than 0.2mm/year. Due to the higher chromium content of duplex stainless steel, it has good corrosion resistant in many corrosive catalyst. 

  Pitting and crevice corrosion can be increased with the content of chromium, molybdenum, and nitrogen.Salt spray test can get the critical pitting temperature - CPT.Pitting occurred urder this temperature.ASTM g48 method F - the measurement temperature in crevice corrosion temperature CPT under 6% FeCl3 + 1% HC - CCT. Different products and different surface treatments may show the different CCT value from the following figure. 

  Austenitic Stainless Steel may occur stress corrosion cracking -SSC in high temperature oxidiferous.Duplex Stainless Steel is difficult to have this kind of corrosion. The test result is shown on the CCT figure. It's obvious that the Duplex Stainless Steel is better than 304L, 316L, and Austenitic Stainless Steel. 

  It will increase the risk of SSC when hydrogen sulfide and chlorides are in the environment.This environment will exizt in oil well drilling. S31803 has been proved to have good resistant of SSC. NACE MR0175 (National Associattion of Corrosion Engineers- the sulfide stress cracking resistant and stress corrosion of metal in high sulfur content oil field environment )has approved this material. 


  Duplex structure and low carbon content result in good intergranlur corrosion resistant of Duplex Stainless Steel. The composition ensures the newly formed Austenitic phase in heat affted area after the welding. This will greatly decrease the risk of carides and nitrides at the grain boundary.


  Combining the high hardness and good corrosion resistant, Duplex Stainless Steel has excellent erosion resistant. Therefore, it has good benefit if applying in the fluid containing particles of erosion in wear and tear on teastructure, such as carrying the sand and salt crystals in the piping system. High mechanical strength and excellent corrosion resistant provid the extremly high corrosion fatigue resistant. Accoring to 2205 and 316L S-N curve in artifical seawater shows the corrosion fatigue resistant in 2005 is much higher than in 316L.

DUPLEX 2205 Stainless Steel

Chemical Compositions:

 

UNS

C

Si

Mn

P

S

Cr

Ni

Mo

N

S31803

≤0.030

≤1.00 

≤2.00 

≤0.030

≤0.020

21.0-23.0 

4.5-6.5 

2.5-3.5

0.08-0.20

S32205

≤0.030

≤1.00 

≤2.00 

≤0.030

≤0.020

22.0-23.0 

4.5-6.5 

3.0-3.5

0.14-0.20

 

 

Mechanical Properties (ASTM A182):

 

UNS

Yield Strength

Tensile Strength

Elongation

R.A. %

Hardness

S31803(F51)

≥450MPa

≥620MPa

≥25%

≥45%

--

S32205(F60)

≥450MPa

≥655MPa

≥25%

≥45%

--

 

 

 

Characteristics:

 

    UNS S31803  and  UNS S32205 are also called Duplex 2205, including almost the same percentage of Ferrite and Austenite mixed structure. That's why Duplex comes from. In more than 70 years ago, it was developed by Sweden. In Sulfite paper industry, it is used to overcome the corrosion problem in bearing cold water and other corrosive chemicals. Then, taking Nitrogen as alloying agent deliberately, the Nitrogen quickly became the mainstream alloy composition in Duplex Stainless Steel. 

 

     When talking about  Duplex 2205, it mens UNS S31803/F51 or UNS S32205/F60.  The UNS  S32205/F60  is corresponding to  the higher range of corrosion resistant components. It means  that the UNS S32205  has higher  contents of  chromium, nitrogen, and molybdenum. This ensures the better corrosion resistant for UNS S32205. Usually, the mill will produce the UNS S32205 to match the chemical composition reauirement for both UNS S31803 and UNS S32205.

 

 

Applications

  • Chemical, paper, oil refining industry
  • Desalination equipment, water systems
  • Chemical tankers and cargo piping system
  • Offshore platform fire and blast walls
  • Bridges, structural design elements
  • Pressure vessels, heat exchangers
  • Turbine blades and drive shaft   

 

 

More informaiton about the corrosion resistant in Duplex Stainless Steel, please contact with us.